In this course, we will discuss the physical chemistry behind electrochemical reactions (or electron transfer processes more generally) and methods to elucidate mechanisms. In particular, we discuss the thermodynamics and kinetics of electrode processes. This involves both classical theories of electrode kinetics as well as modern microscopic theory. We will cover electron transfer processes and coupled homogeneous reactions as well as homogeneous electrocatalysis and transport processes. We treat electrochemical methods such as controlled potential, controlled current, pulsed, hydrodynamic methods and impedance as well as scanning probe and spectroelectrochemical methods and other coupled characterization. Along these topics, we cover current research lines in energy storage, electrosynthesis, and biomolecular electron transfer processes.

Target group: Students with background in chemistry, materials science, physics, or biology.
I particularly also cover topics relevant for life science students interested in electron transfer reactions.

Prerequisites: Basic knowledge in physical chemistry will be beneficial.

Evaluation: Active participation in course (50%), recitation (50%)

Teaching format: The course will consist of 2 lectures per week and a weekly open discussion session. During the discussion session, we will discuss 2 papers concerning the material covered the previous week, which the students will have to read prior to the discussion session. Every week, 2 different students will summarize the papers as a starting note for the discussion.

ECTS: None Year: 2024

Track segment(s):
Elective

Teacher(s):
Stefan Freunberger

Teaching assistant(s):